(2-Formyl-6-methoxyphenolato-κ2 O 1,O 2)(perchlorato-κO)(1,10-phenanthroline-κ2 N,N′)copper(II)
نویسندگان
چکیده
In the title mol-ecule, [Cu(C(8)H(7)O(3))(ClO(4))(C(12)H(8)N(2))], the Cu(II) ion is five-coordinated by two N atoms [Cu-N = 1.995 (3) and 2.022 (3) Å] from a 1,10-phenanthroline ligand, two O atoms [Cu-O = 1.908 (2) and 1.927 (2) Å] from an o-vanillin ligand and one O atom [Cu-O = 2.510 (3) Å] from a perchlorate anion in a distorted square-pyramidal geometry. Three O atoms of the perchlorate anion are rotationally disordered between two orientations, with occupancies of 0.525 (13) and 0.475 (13). In the crystal structure, two mol-ecules related by a centre of symmetry are paired in such a way that the phenolate O atom from one mol-ecule completes the distorted octa-hedral Cu coordination in another mol-ecule [Cu⋯O = 2.704 (2) Å].
منابع مشابه
Di-μ-oxido-bis[(4-formyl-2-methoxyphenolato-κO 1)oxido(1,10-phenanthroline-κ2 N,N′)vanadium(V)]
The title complex, [V(2)(C(8)H(7)O(3))(2)O(4)(C(12)H(8)N(2))(2)], is a centrosymmetric dimer formed by two V(V) complex units bridged by two μ(2)-oxido groups. The V(V) atom is six-coordinated by three oxide O atoms, one O atom from a vanillinate ligand and two N atoms from a 1,10-phenanthroline ligand in a significantly distorted octa-hedral geometry. In the crystal structure, weak inter-molec...
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In the structure of the title complex, [Cu(C(8)H(4)O(4))(C(12)H(8)N(2))(H(2)O)]·CH(4)O, the Cu(II) ion is penta-coordinated in a tetra-gonal-pyramidal geometry, with two O atoms of the 3-formyl-2-oxidobenzoate (3-formyl-salicylate) anion and two N atoms of 1,10-phenanthroline occupying the basal plane, and a water O atom located at the apical site. The structure displays O-H⋯O hydrogen bonding.
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